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Excessively high intake of certain B-vitamins can also cause headaches: Vitamin B6 (Pyridoxine): High doses of vitamin B6 can lead to neurological issues, including headaches, sensory neuropathy, and other symptoms such as numbness and tingling in the extremities

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The key regulators are the nicotinamide adenine dinucleotides (NADs) - the bodily forms of vitamin B3 - and the glutathione forms