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This may well be due to the dense packing and preorganisation of the hydrocarbon chains in the lipid bilayer of the liposomes, which allows the catalyst to easily interact with fatty acid residues of two separate molecules, whereas in solution the lipids will be more dilute at the same concentration and intramolecular OM is far more likely

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doi: 10.1016/j.biopsych.2009.04.033 140 ShadfarS.ParakhS.JamaliM