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This variation occurs with multiple oxidants and is shown to arise from favorable electrostatic stabilization of the incipient positive charge on the sulfur reaction center by remote groups, or by the neighboring sulfur for conformations in which the orbitals are suitably aligned

Cunha-Oliveira T, et al

7B and Supplementary Figure S4)

However, taking it with food may reduce gastrointestinal side effects (particularly heartburn and nausea), which can be significant at higher doses [1]