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doi: 10.1016/j.biomaterials.2005.02.002 242 KimHJChoHBLeeSLyuJKimHRLeeSet al

While glutathione itself crosses this barrier poorly, the brain can synthesize glutathione from precursor amino acids, and systemic glutathione elevation may indirectly support brain glutathione status through various mechanisms including reduced oxidative stress on blood-brain barrier integrity and improved availability of glutathione precursors

In the animals given high doses of caffeine and paraxanthine cGMP, catalase and BDNF levels were all increased though this effect was seeen more strongly in those given paraxanthine

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It also induces oxidative stress, damaging Sertoli and Leydig cells critical for sperm production (65)