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The occurrence of these equilibria between the different thiol-bound forms of mercury, including the neurotoxic methyl-mercury, and of cadmium has been demonstrated to occur as exemplified in Scheme 4 for mercury, through Nuclear Magnetic Resonance experiments both of biomimetic models [37,38,39] and of intact erythrocytes [39,40,41,42]

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HLRCCs FH inactivation-induced fumarate accumulation and GPX4 dysfunction (231) also lack downstream mechanistic dissection