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4.5 Metabolic dysregulation 4.5.1 Insulin signaling pathways in obesity and metabolic disease Metabolic tissues develop lipid intermediates alongside altered adipokine expression profiles and compromised mitochondrial function, progressively attenuating insulin responsiveness (65)

Des-IGF-1 affects glutamate receptor AMPAR binding protein (GRIP), N-ethylmaleimide-sensitive fusion protein (NSF), stargazin, and proteins that interact with C-kinase-1, which influence AMPA receptor anchoring, surface translocation, and synaptic targeting [72]

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For example, excess copper in plants can form a hydroxyl radical from H 2 O 2 via the Haber-Weiss cycle ( Figure 3 3.4 Impact of exogenous ergothioneine on the pyridine dinucleotide profiles of stored broccoli NADPH is required as a cofactor for many metabolic processes in plants, including the major ROS-generating enzyme NADPH-dependent oxidase activity, as well as the electron donor-driving GR activity in the ascorbate-GSH recycling pathway ( Figure 4 )